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PROCESS GCs
Introduction
The Model 301-C PGCs are flexible
PID-Description
The process of photoionization is initiated by
the absorp-tion of a photon of ultraviolet
radiation energetic enough to ionize a
molecule (RH) by the process shown below:
RH + h RH+ + ewhere h represents a photon with an energy
the ionization potential of species RH. The
ions are collected in an ionization chamber
which is adjacent to the lamp and contains an
accelerat-ing electrode (biased positively) and
a collection electrode where the current is
measured. After amplification, the current
measured is proportional to concentration. The
response measured will be a summation (total)
of the hydrocarbons ionized.
FID Description
In the FID, the sample is burned in a hydrogenair flame and the ions formed from carbon
containing compounds are collected by
applying a positive potential to the jet and
measuring the current at collection electrode
just above the flame. After amplification, the
current measured is proportional to
concentration. The response measured will be
a summation (total) of the hydrocarbons
ionized.
TCD Description
Measures difference between the thermal
transfer characteristics of the sample gas and
a reference gas, generally helium. The sample
and reference filaments are two legs of a
Wheatstone Bridge. A constant current is
PROCESS GCs
Specifications
Detectors available: PID , TCD,
FID, FUV, ECD, FPD (S, P)
Measurement mode: Continuous
Zero drift- Automatic Zero
compensation; <1% per month
Span drift- Auto cal each 24 hours
(remotely with contact closure):
less than 1% every 24 hours
Wide range of response- from sub
ppm on PID to % on the FID or TCD
Support gases:FID & FPD require
H2 and zero air
Readout- Color VGA display
Standard output: 1 VDC, RS232
Enclosures:Rack (NEMA 2)
19" W x 11"H x 17"D
Weight: 32 pounds
Wall (NEMA 4)- 301C
23"W x 30"H x 17"D
Options
Gas or liquid sampling systems
4-20 mA output; RS485 output,
10/100 network card,
See Table I
Data acquisition and storage using
PeakWorks C- runs under
Windows or Windows NT on a
Remote Pentium PC
2, 4-6, 8-12 point sequencers for 301C; 16-20,20+ point sequencers
-(with contact closure to indicate point
being
sampled,
Display
of
Concentration, Sampling Point & Sample
Flow (measured by flowmeter)
Mass flow sensor for column flow optional for 301 C
Applications Engineering:Dual columns,
column switching valves, concentrator
X or Z purged for Zone 1 and Zone 2
respectively- requires NEMA enclosure
Weight: 80 pounds-301C
Sampling Systems
Table I
Comparison of Model 301C Process GCs
Model 301 C
Enclosures
19 Rack
NEMA 4
Separate enclosure for GC
foven
Second oven
Purged enclosures (X orZ)
No
Optional
Multipoint Sequences
Optional
Optional
Optional
Optional
Optioal
Optioal
Pentium PC
VGA Display
Operating System
Yes
Yes
Windows XP embedded
Chromatography Data
PeakWorks
PeakWorks C SW
MODBUS
RS232
0-1 VDC
4-20 mA
Option
Option
Included
Included
Optional per point/per component
Yes
Yes optional
No optional
Definitions
MODBUS- communications protocol that allows
extrnal PC or PLC to request data
PeakWorks- Windows based chromatography
data & analyzer control software
PeakWorks C-Communications software run on
a remote PC (through the RS232 port) that displays and stores data remotely
Sample ahead-sampling for the next point
starts as son as sample is injected- faster sampling times
Sample point programming-Instead of
sample points being 1,2,3... they can be customer programme to 1,1,5,9,1...
Additioonal valve relay- more complex analyses can be run
PeakWorksTM
Multipoint Sequencer