| A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | |
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1 | In a screw-top vial | |||||||||||||||||||||||||
2 | Metal cation // amount (mmol) | Ligand amount (mmol) | Solvent // amount (mL) | Acid/Base* // amount (mL) | Duration in oven (h) | Notes | ||||||||||||||||||||
3 | Mn2+// 0.050 | 0.05 | H2O // 2 | N/A | 19 | [before oven] Milky off-white suspension [after oven] Ligand settled out into clump at bottom of vial | ||||||||||||||||||||
4 | Co2+// 0.050 | 0.05 | H2O // 2 | N/A | 19 | [before oven] Light pink suspension [after oven] Ligand settled out | ||||||||||||||||||||
5 | Cu2+// 0.050 | 0.05 | H2O // 2 | N/A | 19 | [before oven] Light blue suspension [after oven] Solution, darker blue, no crystals | ||||||||||||||||||||
6 | Ni2+// 0.050 | 0.05 | H2O // 2 | N/A | 19 | [before oven] Light green suspension [after oven] Solution, nocrystals | ||||||||||||||||||||
7 | Zn2+// 0.050 | 0.05 | H2O // 2 | N/A | 19 | [before oven]Whitesuspension [after oven] Ligand settled out | ||||||||||||||||||||
8 | Mn2+// 0.050 | 0.05 | H2O // 2 | NaOH // 0.35 | 19 | [before oven]Off-white suspension [after oven]Ligand settled out | ||||||||||||||||||||
9 | Co2+// 0.050 | 0.05 | H2O // 2 | NaOH // 0.35 | 19 | [before oven] Purple-pink suspension [after oven] Two layers, transparent and opaque | ||||||||||||||||||||
10 | Cu2+// 0.050 | 0.05 | H2O // 2 | NaOH // 0.35 | 19 | [before oven] Blue suspension [after oven] Blue suspension | ||||||||||||||||||||
11 | Ni2+// 0.050 | 0.05 | H2O // 2 | NaOH // 0.35 | 19 | [before oven] Light green suspension [after oven] Greenish suspension | ||||||||||||||||||||
12 | Zn2+// 0.050 | 0.05 | H2O // 2 | NaOH // 0.35 | 19 | [before oven] Off-white suspension [after oven] Grayish suspension | ||||||||||||||||||||
13 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.2 | 66 | [beforeoven] clear blue solution [after oven] clear blue solution | ||||||||||||||||||||
14 | Cu2+// 0.050 | 0.05 | NMP //2.00 | TEOA // 0.2 | 66 | [beforeoven] cloudy greenish-blue suspension [after oven] brown-black residue | ||||||||||||||||||||
15 | Cu2+// 0.050 | 0.05 | MeOH// 2.00 | TEOA // 0.2 | 66 | [before oven] cloudy blue-green solution [after oven] brown solution with greenpowder | ||||||||||||||||||||
16 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 8 | [before oven]clear blue solution [after oven]blue-green microcrystals | ||||||||||||||||||||
17 | Cu2+// 0.050 | 0.05 | H2O &MeOH(1:1 ratio) // 2.00 | TEOA // 0.1 | 48 | [before oven] clear-ishblue solution [afteroven] brown-black residue | ||||||||||||||||||||
18 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.05 | 50 | [beforeoven] slightly cloudy blue solution [after oven] clear blue solution | ||||||||||||||||||||
19 | Cu2+// 0.050 | 0.05 | H2O//2.00 | TEOA // 0.075 | 50 | [beforeoven] clear blue solution [after oven] clear solution of a slightly lighter blue | ||||||||||||||||||||
20 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.125 | 50 | [before oven]clear blue solution [after oven] clear blue solution | ||||||||||||||||||||
21 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.15 | 50 | [before oven] clear blue solution [after oven] murky, thick brown solution | ||||||||||||||||||||
22 | Cu2+// 0.025 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 50 | [beforeoven] light blue solution [after oven] clear solution with moss green powder at bottom | ||||||||||||||||||||
23 | Cu2+// 0.040 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 50 | [before oven] lightblue solution [after oven] murky, viscous green solution | ||||||||||||||||||||
24 | Cu2+// 0.075 | 0.05 | H2O//2.00 | TEOA // 0.1 | 50 | [beforeoven] clear blue solution [after oven] viscous moss green solution | ||||||||||||||||||||
25 | Cu2+// 0.10 | 0.05 | H2O// 2.00 | TEOA // 0.1 | 50 | [before oven] clear blue solution [after oven] reddish-brown residue | ||||||||||||||||||||
26 | Cu2+// 0.15 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 50 | [before oven]clear blue solution [after oven] green residue | ||||||||||||||||||||
27 | Cu2+// 0.050 | 0.05 | H2O & DMF (1:1 ratio) // 2.00 | TEOA // 0.1 | 43 | [beforeoven] slightly cloudy blue solution [after oven] murky chocolate brown suspension | ||||||||||||||||||||
28 | Cu2+// 0.050 | 0.05 | NMP//2.00 | TEOA // 0.1 | 43 | [beforeoven] slightly cloudy blue solution [after oven] wine colored solution | ||||||||||||||||||||
29 | Mn2+// 0.050 | 0.05 | H2O// 2.00 | TEOA // 0.1 | 50 | [before oven] whitish suspension [after oven] ligand settled out on bottom | ||||||||||||||||||||
30 | Ni2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 50 | [before oven]clear green solution [after oven] viscous brownish solution | ||||||||||||||||||||
31 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEA // 0.05 | 27 | [beforeoven] cloudy bluesolution [after oven] cloudy blue solution | ||||||||||||||||||||
32 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | TEA // 0.1 | 27 | [beforeoven] clear bluesolution [after oven] clear blue solution | ||||||||||||||||||||
33 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | DMA // 0.05 | 27 | [beforeoven] cloudy bluesolution [after oven] cloudy blue solution | ||||||||||||||||||||
34 | Cu2+// 0.050 | 0.05 | H2O // 2.00 | DMA // 0.1 | 27 | [beforeoven] clear bluesolution [after oven] clear blue solution | ||||||||||||||||||||
35 | Zr4+// 0.050 | 0.05 | H2O // 2.00 | none | 47 | [beforeoven] cloudy off-white suspension [after oven] cloudy, viscous off-white suspension | ||||||||||||||||||||
36 | Fe3+// 0.050 | 0.05 | H2O//2.00 | 0.075 | 48 | [beforeoven] cloudy brown suspension [after oven] light golden-brown gel | ||||||||||||||||||||
37 | Ni2+ // 0.10 | 0.05 | THF // 2.25 | none | 16 | [beforeoven] cloudy green suspension [after oven] green powder | ||||||||||||||||||||
38 | Ni2+ // 0.10 | 0.05 | H2O // 2.00 | TEA // 0.05 | 16 | [beforeoven] cloudy green suspension [after oven] green powder + brown residue | ||||||||||||||||||||
39 | Ni2+ // 0.10 | 0.05 | H2O // 2.00 | TEA // 0.1 | 16 | [beforeoven] cloudy green suspension [after oven] green powder + brown residue | ||||||||||||||||||||
40 | Cu2+ // 0.05 | 0.05 | H2O // 2.00 | TEA // 0.1 | 16 | [beforeoven] cloudy blue suspension [after oven] cloudy blue suspension | ||||||||||||||||||||
41 | Cu2+ // 0.10 | 0.05 | H2O // 2.00 | TEA // 0.1 | 16 | [beforeoven] cloudy blue suspension [after oven] cloudy blue suspension | ||||||||||||||||||||
42 | Ni2+ // 0.10 | 0.05 | THF // 5.00 | HCl // 0.05 | 16 | [beforeoven] cloudy green suspension [after oven] solution w/ green powder settled out | ||||||||||||||||||||
43 | Cu2+ // 0.10 | 0.05 | THF // 5.00 | HCl // 0.05 | 16 | [beforeoven] cloudy blue suspension [after oven] solution w/ blue powder settled out | ||||||||||||||||||||
44 | Ni2+ // 0.10 | 0.05 | DMF // 5.00 | HCl // 0.05 | 16 | [beforeoven] cloudy green suspension [after oven] cloudy green suspension | ||||||||||||||||||||
45 | Cu2+ // 0.10 | 0.05 | DMF // 5.00 | HCl // 0.05 | 16 | [beforeoven] cloudy blue suspension [after oven] cloudy blue suspension | ||||||||||||||||||||
46 | Zn2+ // 0.10 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 41 | [beforeoven] clear solution [after oven] black-brown solution | ||||||||||||||||||||
47 | Fe3+ // 0.10 | 0.05 | DMSO // 2.00 | none | 41 | [beforeoven] cloudy golden suspension [after oven] black gel-like solution | ||||||||||||||||||||
48 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.10 | 96 | [beforeoven] cloudy pink suspension [after oven] solution w/ pink powder settled out | ||||||||||||||||||||
49 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.15 | 96 | [beforeoven] cloudy pink suspension [after oven] solution w/ pink powder settled out | ||||||||||||||||||||
50 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.20 | 96 | [beforeoven] cloudy pink suspension [after oven] solution w/ pink powder settled out | ||||||||||||||||||||
51 | Cu2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.10 | 96 | [beforeoven] cloudy blue suspension [after oven] solution w/ blue powder settled out | ||||||||||||||||||||
52 | Cu2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.15 | 96 | [beforeoven] clear blue solution [after oven] solution w/ blue powder settled out | ||||||||||||||||||||
53 | Cu2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.20 | 96 | [beforeoven] clear blue solution [after oven] solution w/ blue powder settled out | ||||||||||||||||||||
54 | Ni2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.10 | 96 | [beforeoven] cloudy green suspension [after oven] solution w/ green powder settled out | ||||||||||||||||||||
55 | Ni2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.15 | 96 | [beforeoven] light green solution [after oven] solution w/ green powder settled out | ||||||||||||||||||||
56 | Ni2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.20 | 96 | [beforeoven] light green solution [after oven] solution w/ green powder settled out | ||||||||||||||||||||
57 | Mn2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.10 | 96 | [beforeoven] cloudy yellow/off-white suspension [after oven] solution w/ yellow powder settled out | ||||||||||||||||||||
58 | Mn2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.15 | 96 | [beforeoven] cloudy yellow/off-white suspension [after oven] solution w/ yellow powder settled out | ||||||||||||||||||||
59 | Mn2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.20 | 96 | [beforeoven] clear yellowish solution [after oven] separated into two layers -- clear and powdery yellow -- clear microcrystals | ||||||||||||||||||||
60 | Eu2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.20 | 23 | [before oven] milky suspension [after oven] white gel | ||||||||||||||||||||
61 | Eu2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.15 | 23 | [before oven] milky suspension [after oven] white gel | ||||||||||||||||||||
62 | Eu2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.10 | 23 | [before oven] milky suspension [after oven] white gel | ||||||||||||||||||||
63 | Eu2+ // 0.10 | 0.033 | H2O // 2.00 | NaOH // 0.13 | 23 | [before oven] milky suspension [after oven] white gel | ||||||||||||||||||||
64 | ||||||||||||||||||||||||||
65 | In a Teflon-lined autoclave | |||||||||||||||||||||||||
66 | Metal cation // amount (mmol) | Ligand amount (mmol) | Solvent // amount (mL) | Base // amount (mL) | Duration in oven (h) | Notes | ||||||||||||||||||||
67 | Ni2+// 0.050 | 0.05 | H2O // 2.00 | TEOA // 0.05 | 70 | [beforeoven] cloudy light green suspension [after oven] cloudy brownish suspension | ||||||||||||||||||||
68 | Ni2+// 0.10 | 0.05 | H2O // 2.00 | TEOA // 0.05 | 70 | [before oven] cloudy light greensuspension [after oven] cloudy brownish suspension | ||||||||||||||||||||
69 | Ni2+// 0.050 | 0.05 | H2O//2.00 | TEOA // 0.1 | 70 | [beforeoven] clear light green solution [after oven] cloudy brownish suspension | ||||||||||||||||||||
70 | Ni2+// 0.10 | 0.05 | H2O// 2.00 | TEOA // 0.1 | 70 | [before oven] clear light green solution [after oven] cloudy brownish suspension with thin crystalline film | ||||||||||||||||||||
71 | Ni2+// 0.15 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 41 | [beforeoven] cloudy light greensuspension [after oven] cloudy light green suspension | ||||||||||||||||||||
72 | Ni2+// 0.15 | 0.05 | H2O // 2.00 | TEOA // 0.15 | 41 | [before oven] cloudy light greensolution [after oven] cloudy light green suspension | ||||||||||||||||||||
73 | Ni2+// 0.20 | 0.1 | H2O//2.00 | TEOA // 0.2 | 41 | [beforeoven] cloudy light greensolution [after oven] cloudy light green suspension | ||||||||||||||||||||
74 | Ni2+// 0.20 | 0.1 | H2O// 2.00 | TEOA // 0.1 | 41 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
75 | Ni2+ // 0.10 | 0.05 | THF // 5.50 | TEOA // 0.05 | 41 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
76 | Ni2+ & Cu2+ // 0.05 both | 0.05 | H2O // 5.00 | none | 41 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
77 | Ni2+ & Cu2+ // 0.05 both | 0.05 | H2O // 5.00 | TEOA // 0.05 | 41 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
78 | Ni2+ & Cu2+ // 0.05 both | 0.05 | H2O // 5.00 | TEOA // 0.1 | 41 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
79 | Ni2+ & Cu2+ // 0.05 both | 0.05 | H2O // 5.00 | TEOA // 0.015 | 41 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
80 | Ni2+ // 0.20 | 0.1 | H2O // 5.00 | none | 70 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
81 | Ni2+ // 0.10 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 70 | [before oven] cloudy light greensolution [after oven] cloudy lightgreen suspension | ||||||||||||||||||||
82 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | none | 41 | [before oven] cloudy pink suspension [after oven] cloudy pink suspension | ||||||||||||||||||||
83 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | TEOA // 0.05 | 41 | [before oven] cloudy pink suspension [after oven] cloudy pink suspension | ||||||||||||||||||||
84 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | TEOA // 0.1 | 41 | [before oven] cloudy pink suspension [after oven] cloudy brown suspension | ||||||||||||||||||||
85 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | DEA // 0.1 | 41 | [before oven] cloudy pink suspension [after oven] cloudy pink suspension | ||||||||||||||||||||
86 | Co2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.18 | 48 | [before oven] cloudy pink suspension [after oven] cloudy pink suspension | 220C | |||||||||||||||||||
87 | Mn2+ // 0.10 | 0.05 | H2O // 2.00 | NaOH // 0.20 | 48 | [before oven] cloudy off-white solution [after oven] brown suspension | 220C | |||||||||||||||||||
88 | Mn2+ // 0.10 | 0.05 | H2O // 2.00 | TEOA // 0.05 | 48 | [before oven] cloudy off-white solution [after oven] brown suspension suspension | 220C | |||||||||||||||||||
89 | ||||||||||||||||||||||||||
90 | Evaporated | |||||||||||||||||||||||||
91 | Metal cation // amount (mmol) | Ester amount (mmol) | Solvent // amount (mL) | Base // amount (mL) | Duration in fume hood (h) | Notes | ||||||||||||||||||||
92 | Cu2+ // 0.10 | 0.05 | MeOH // 2.00 | none | 120 | [before] clear yellow-green solution [after] green crystals | ||||||||||||||||||||
93 | ||||||||||||||||||||||||||
94 | Trials w/ Phosphodiester | |||||||||||||||||||||||||
95 | Metal cation // amount (mmol) | Ester amount (mmol) | Solvent // amount (mL) | Acid/Base // amount (mL) | Duration in oven (h) | Notes | ||||||||||||||||||||
96 | Zn2+ // 0.10 | 0.05 | H2O // 2.00 | none | 23 | [before] clear yellow solution [after] off-white solution w/ floating opaque particles | ||||||||||||||||||||
97 | Zn2+ // 0.10 | 0.05 | MeOH // 2.00 | none | 23 | [before] clear yellow solution [after] yellow powder | ||||||||||||||||||||
98 | Zn2+ // 0.10 | 0.05 | MeOH, H2O, DMF // 0.6 : 2.4 : 4.4 respectively | none | 23 | [before] clear yellow solution [after] yellowish solution with floating white particles | ||||||||||||||||||||
99 | Zn2+ // 0.10 | 0.05 | H2O // 2.00 | HCl // 0.5 mL | 67 | [before] clear yellow solution [after] transparent solution with spiky clear crystals | ||||||||||||||||||||
100 | ||||||||||||||||||||||||||